首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   16842篇
  免费   2694篇
  国内免费   1917篇
化学   12188篇
晶体学   177篇
力学   1182篇
综合类   138篇
数学   2071篇
物理学   5697篇
  2023年   322篇
  2022年   323篇
  2021年   475篇
  2020年   621篇
  2019年   649篇
  2018年   512篇
  2017年   532篇
  2016年   740篇
  2015年   745篇
  2014年   929篇
  2013年   1155篇
  2012年   1514篇
  2011年   1555篇
  2010年   1055篇
  2009年   942篇
  2008年   1097篇
  2007年   990篇
  2006年   985篇
  2005年   800篇
  2004年   606篇
  2003年   537篇
  2002年   499篇
  2001年   446篇
  2000年   323篇
  1999年   334篇
  1998年   293篇
  1997年   264篇
  1996年   286篇
  1995年   233篇
  1994年   203篇
  1993年   157篇
  1992年   170篇
  1991年   173篇
  1990年   132篇
  1989年   121篇
  1988年   80篇
  1987年   69篇
  1986年   82篇
  1985年   60篇
  1984年   54篇
  1983年   44篇
  1982年   32篇
  1981年   31篇
  1980年   29篇
  1978年   24篇
  1977年   25篇
  1976年   23篇
  1975年   18篇
  1974年   20篇
  1973年   26篇
排序方式: 共有10000条查询结果,搜索用时 198 毫秒
991.
Air-breathing mode laser propulsion experiment with a long-pulse transversely excited(TE) CO2 laser is carried out,and its ignition problem is solved with the ignition needle of lightcraft.Owing to the ignition needle,an order of magnitude reduction in the ignition threshold is demonstrated.The result is compared with previous study.The momentum coupling coefficient is also measured in the experiment and its dependence upon laser pulse energy(6-14 J) and pulse width(20,32,and 40μs) is discussed.  相似文献   
992.
根据高炉冲渣水的余热特点,提出了一个采用分离式热管换热器的余热回收的方案。文中对余热回收方案中换热设备的结构特点进行了描述。  相似文献   
993.
System calibration, which usually involves complicated and time-consuming procedures, is crucial for any three-dimensional (3D) shape measurement system based on vision. A novel improved method is proposed for accurate calibration of such a measurement system. The system accuracy is improved with considering the nonlinear measurement error created by the difference between the system model and real measurement environment. We use Levenberg-Marquardt optimization algorithm to compensate the error and get a good result. The improved method has a 50% improvement of re-projection accuracy compared with our previous method. The measurement accuracy is maintained well within 1.5% of the overall measurement depth range.  相似文献   
994.
The first version of Acta Mechanica Sinica (AMS) was launched in June 1985 in Beijing, aimed at delivering the cutting-on-edge progress and achievement in Mechanics in China to the world, allowing world-round colleagues to access the work of Chinese mechanician, and supplying an international forum in the field. Its appearance was a result of 5-year preparation after the consensus agreement by the Acta Mechanica Sinica Editorial Board (3rd), and was approved by the China Association for Science and Technology and supported by the Chinese Society of Theoretical and Applied Mechanics (CSTAM).  相似文献   
995.
Two new coordination polymers, [Na(H2L)(H2O)2]n ( 1 ) and [Ba(H2L)2(H2O)]n ( 2 ) (H3L = 3‐formyl‐4‐hydroxybenzenesulfonic acid) were synthesized and structurally characterized. The H2L ligand shows three different bridging modes, μ3 in 1 , μ3 and μ4 in 2 . Compound 1 presents a 2D pillared structure, whereas 2 forms a 3D framework. Both 1 and 2 show blue luminescence at 380 nm in aqueous solution, however, their solid state emissions are at 406 and 446 nm, respectively.  相似文献   
996.
A series of highly organosoluble polyamides with high modulus having propeller‐shaped triarylamine were synthesized using aromatic diacid chlorides by low‐temperature solution polycondensation. The polyamide films had strong, tough, flexible, and amorphous properties. These polymers revealed electrochromic characteristics both in the visible range and near‐infrared (NIR) region, with a color change from pale yellowish at its neutral state to green and blue at its oxidized state at applied potentials ranging from 0.00 to 1.35 V. Cyclic voltammetry (CV) of the polymer films cast onto an indium tin oxide (ITO)‐coated glass substrate exhibited two reversible redox couples at potentials of 0.80–0.87 V and 1.19–1.25 V, respectively, vs. Ag/Ag+ in acetonitrile solution. From the combination of the experimental and computational study, we proposed an oxidation mechanism based on molecular orbital (MO) theory, which well explains the CV experimental result. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010  相似文献   
997.
基于ST7LITEF15B单片机研制了用于实验教学的低成本液体电导率传感器. 介绍了测试方案、系统的硬件结构和软件的设计思路,进行了典型标样的测量实验,结果表明该液体电导率传感器的研制是成功的.  相似文献   
998.
The structures of Nafion membranes prepared by solutions casting from low aliphatic alcohols/water mixture solvents and N,N′‐dimethyl formamide (DMF) solvent were investigated using differential scanning calorimeter and small angle X‐ray scattering. The aggregation behavior of Nafion molecules in the casting solutions was also investigated using dynamic light scattering. We show that the morphology of membranes was strongly influenced by the conformations of Nafion molecules in the solutions. In aliphatic alcohol/water mixture solvents, which have a worse compatibility with Nafion backbones, the Nafion molecules aggregate and form fringed rod‐like structures. These primary rod‐like structures then aggregate again through fringed side chains to form secondary ionic aggregations. In DMF solvent, owing to its better compatibility with Nafion backbones, less Nafion molecules aggregate. The high degree of Nafion molecular aggregations in aliphatic alcohol/water mixture solvents leads to a high degree of hydrophobic and hydrophilic phase separation for membranes prepared by casting from Nafion/aliphatic alcohol/water solutions. However, the lower degree of molecular aggregations in DMF solvent results in a lower degree of hydrophobic and hydrophilic phase separation for membranes prepared by casting from Nafion/DMF solution. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 3044–3057, 2005  相似文献   
999.
Numerous efforts towards synthesis of anticancer drug paclitaxel (Taxol(r), 1a) with improved activities led to the modification at 13-phenylisoserine side chain and different positions of its core structure-baccatin III 1c1. At the same time, the activities of searching new taxoids for starting materials of new semi-synthetic paclitaxel analogs from Taxus spp. plant have not ever been stopped. Among these taxoids, 14?-hydroxy-10-deacetylbaccatin III 22 and 13-acetyl-9-dihydrobaccatin III …  相似文献   
1000.
A highly homogeneous and nearly monophasic PrBa2Cu4O8 compound has been synthesized at 1 atm of oxygen via a route employing polymeric ethylenediamine/citric acid precursors. The PrBa2Cu4O8 compound with a trace amount of BaCuO2 was synthesized for the first time by sintering the pellets at the temperature of 875 °C under ambient oxygen pressure. The temperature coefficient of the resistivity is positive below 190 K while above 190 K is negative. The superconducting transition was not detected down to 4.2 K. Samples were characterized by X-ray diffraction, scanning electron microscopy, thermal analysis, and transport and magnetic measurements.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号